Halogen Bonding Interactions in DDQ Charge Transfer Salts with Iodinated TTFs
نویسندگان
چکیده
منابع مشابه
Halogen Bonding Interactions in DDQ Charge Transfer Salts with Iodinated TTFs
Oxidation of 3,4-ethylenedithio-3'-iodo-tetrathiafulvalene (EDT-TTF-I) and 3,4-ethylenedithio-3',4'-diiodo-tetrathiafulvalene (EDT-TTF-I2) with DDQ afforded two different salts formulated as (EDT-TTF-I)(DDQ) and (EDT-TTF-I2)2(DDQ)·(CH3CN), both characterized with a full charge transfer to the DDQ acceptor moiety and by short and linear halogen bonding interactions between the iodine atom as hal...
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While an IUPAC definition for hydrogen bonding was only released in 2011 after decades of discussions in the scientific community (Arunann et al., 2011), it did not take such a long time to come up with an analogous definition of halogen bonding (Desiraju et al., 2013), following a revival of this interaction in the literature, which can be traced back to the early 1990s. The identification of ...
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ژورنال
عنوان ژورنال: Crystals
سال: 2012
ISSN: 2073-4352
DOI: 10.3390/cryst2020327